THEFishHead wrote:Dear Doug,
Regarding the clumping, I don't have an answer. Perhaps AAOM science editor Craig Bingman could offer an opinion on this. I have seen the clumping occur and not occur under various circumstances. I do believe that high alkalinity plays an important role, but not exclusively. There may be a biological (bacteria) role. It may not be simply chemistry, but I could be wrong. I can't say whether a calcium reactor would increase the chances of clumping or not.
....
Julian
Sand clumping seems to involve two factors: the degree of CaCO3 saturation in the sand environment, and the biological condition of the sand bed. If the insterstitial water in the sand bed isn't supersaturated with respect to calcium carbonate, you won't get "cementing" of the sand grains. So, anything that increases the saturation state in the system, like adding limewater too fast, adding various calcium and alkalinity supplements, can push up the saturation state and potentiate cementing.
That said, the water flowing over natural coral reefs is supersaturated with respect to both aragonite and calcite, and holding the system at supersaturation is desirable.
The other issue is the biological condition of the sand. Sand loaded with infauna tends to clump less, because it is constantly disturbed. The cement formation seems to start on bacterial coat and exudate proteins, which can aggregate the sand in a sort of soft or gelatenous state. So if you have organisms on patrol that are cleaning up these bacterial aggregates and generally disturbing things, the bacterial mesh will be less elaborated and have less chance of starting the cementing process.
There are some chemical treatments that might make it more likely for sand to develop these aggregates. Heavy use of calcium acetate seems to give the sand bed bacteria plenty to eat, and in some cases can contribute to sand clumping and later sand cementing.
The physical condition of the sand particles also seems to be important. Sand is more likely to cement when it is new. After it has been around for a while, it gets coated with organics that slow calcium carbonate crystal growth.
Overall, there are two things going on here: clumping due to bacterial action and cementing due to calcium carbonate formation. Both seem to be important. With a new sand bed, excess limewater, and little infauna, you are probably going to get both clumping and cementing into hard blocks. Well conditioned sand beds with appropriate amounts of limewater or other supplements, and with well developed infauna seem very resistant to clumping and cementing
Craig Bingman